Optical Sciences

Biomolecules and nanostructures

The Optical Sciences group studies the interaction of light and matter. Our current focus is on detection and sensing/imaging with an emphasis on the development of integrated photonics. We are part of Twente University's Department of Science and Technology and member of the MESA+ institute.

 

Single Molecule Photobleaching Probes the Exciton Wave Function in a Multichromophoric System

(full pdf)

J. Hernando, J.P. Hoogenboom, E.M.H.P. van Dijk, J.J. García-Lopez, M. Crego-Calama, D.N. Reinhoudt, N.F. van Hulst, and M.F. García-Parajó
Physical Review Letters
vol 93 no 23 p 236404 1-4 dec 3, 2004
doi:10.1103/PhysRevLett.93.236404

The exciton wave function of a trichromophoric system is investigated by means of single molecule spectroscopy at room temperature. Individual trimers exhibit superradiance and loss of vibronic structure in emission spectrum, features proving exciton delocalization. We identify two distinct photodegradation pathways for single trimers upon sequential photobleaching of the chromophores. The rate of each pathway is a measure for the contribution of the separate dyes to the collective excited state of the system, in this way probing the wave function of the delocalized exciton. copyright 2004 The American Physical Society
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