Optical Sciences

Biomolecules and nanostructures

The Optical Sciences group studies the interaction of light and matter. Our current focus is on detection and sensing/imaging with an emphasis on the development of integrated photonics. We are part of Twente University's Department of Science and Technology and member of the MESA+ institute.

 

Characterizing the functional dynamics of zinc phthalocyanine from femtoseconds to nanoseconds

(full pdf)

Savolainen J, van der Linden D, Dijkhuizen N, Herek JL
Journal of Photochemistry and Photobiology A- Chemistry
Vol. 196 Issue 1 P99-105 April 30, 2008
doi:10.1016/j.jphotochem.2007.11.018

A promising photosensitizer, zinc phthalocyanine, is investigated by means of steady-state and time-resolved pump-probe spectroscopies. Spectrally resolved pump-probe data are recorded on time scales ranging from femtoseconds to nanoseconds. Global analysis yields the excited-state absorption spectra and lifetimes, as well as the pathways and efficiencies of the competing relaxation processes from the initially excited S-1 state. In addition to the expected nanosecond-scale processes of fluorescence, internal conversion and inter-system crossing that follow the generally accepted kinetic scheme, we also resolve ultrafast dynamics. The nature of these fast processes and their implications to the functional pathway involving triplet formation are discussed. © 2007 Elsevier B.V. All rights reserved.
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